Post on 09-Dec-2015
description
100.8 5
Norit pH=2
pH=2.0 Norit191.4 10 Co Ce Co - Ce qe384.9 23.3 11.1 5.814 5.286 10.6579.3 41.1 22.45 10.242 12.208 24.4751.1 56.4 39.9 22.332 17.568 35.1
1064.9 97.1 61.34 33.19 28.15 56.3100.8 19.4
Merck pH=2
81.9 41.35 40.55 81.1191.4 33 96.7 50.382 46.318 92.6384.9 79.2579.3 103.3751.1 187.3
1064.9 266.799.9 10
Norit pH=4
184.2 10340.1 10 Freundlich experimental561.7 18.5734.3 41.8 Ce qe lnce lnqe955.5 83.1 5 2.4 1.6 0.9
99.9 56.8
Merck pH=4
10 4.5 2.3 1.5184.2 117.9 23.3 9 3.1 2.2340.1 180.1 41.1 13.5 3.7 2.6561.7 210.6 56.4 17.4 4.0 2.9734.3 216.2 97.1 24.2 4.6 3.2955.5 362.1
99.9 13.8184.2 33.9340.1 66.7561.7 117.4734.3 157.1955.5 221.7
Freundlich teórico
lnce lnqe qe1.6 0.9 2.52.3 1.5 4.43.1 2.1 8.23.7 2.6 13.1
4 2.8 16.54.6 3.3 26.5
Langmuir experimental
Ce qe Ce/qe Ce5 2.4 2.1 5
10 4.5 2.2 1023.3 9 2.6 23.341.1 13.5 3.0 41.156.4 17.4 3.2 56.497.1 24.2 4.0 97.1
Langmuir teóricoCe Ce/qe qe
5 2.2 2.310 2.3 4.4
23.3 2.5 9.241.1 2.9 14.356.4 3.2 17.797.1 4.0 24.3
pH=2.0 MerckCo Ce Co - Ce qe
100.8 19.4 81.4 2.0191.4 33 158.4 4.0384.9 79.2 305.7 7.6579.3 103.3 476 11.9751.1 187.3 563.8 14.1
1064.9 266.7 798.2 20.0
Freundlich experimental
Ce qe lnce lnqe19.4 2.0 3.0 0.7
33 4.0 3.5 1.479.2 7.6 4.4 2.0
103.3 11.9 4.6 2.5187.3 14.1 5.2 2.6266.7 20.0 5.6 3.0
Freundlich teórico
lnce lnqe qe3 0.9 2.4
3.5 1.3 3.74.4 2.1 7.84.6 2.2 9.25.2 2.7 15.35.6 3.1 21.5
Langmuir experimental
Ce qe Ce/qe Ce19.4 2 9.7 19.4
33 4 8.3 3379.2 7.6 10.4 79.2
103.3 11.9 8.7 103.3187.3 14.1 13.3 187.3266.7 20 13.3 266.7
Langmuir teóricoCe Ce/qe qe
19.4 8.7 2.233 9.0 3.7
79.2 9.9 8.0103.3 10.4 9.9187.3 12.1 15.5266.7 13.7 19.5
pH=4.0 NoritCo Ce Co - Ce qe
99.9 3.2 96.7 2.4184.2 6.1 178.1 4.5340.1 9.3 330.8 8.3561.7 18.5 543.2 13.6734.3 41.8 692.5 17.3955.5 83.1 872.4 21.8
Freundlich experimental
Ce qe lnce lnqe3.2 2.4 1.2 0.96.1 4.5 1.8 1.59.3 8.3 2.2 2.1
18.5 13.6 2.9 2.641.8 17.3 3.7 2.983.1 21.8 4.4 3.1
Freundlich teórico
lnce lnqe qe1.2 1.2 3.21.8 1.6 4.82.2 1.8 6.22.9 2.3 10.03.7 2.8 17.04.4 3.3 27.1
Langmuir experimental
Ce qe Ce/qe Ce3.2 2.4 1.3 3.26.1 4.5 1.4 6.19.3 8.3 1.1 9.3
18.5 13.6 1.4 18.541.8 17.3 2.4 41.883.1 21.8 3.8 83.1
Langmuir teóricoCe Ce/qe qe
3.2 1.1 2.96.1 1.2 5.09.3 1.3 7.1
18.5 1.6 11.441.8 2.4 17.583.1 3.7 22.2
pH=4.0 MerckCo Ce Co - Ce qe
99.9 13.8 86.1 2.2184.2 33.9 150.3 3.8340.1 66.7 273.4 6.8561.7 117.4 444.3 11.1734.3 157.1 577.2 14.4955.5 221.7 733.8 18.3
Freundlich experimental
Ce qe lnce lnqe13.8 2.2 2.6 0.833.9 3.8 3.5 1.366.7 6.8 4.2 1.9
117.4 11.1 4.8 2.4157.1 14.4 5.1 2.7221.7 18.3 5.4 2.9
Freundlich teórico
lnce lnqe qe2.6 0.7 2.03.5 1.4 4.14.2 2.0 7.14.8 2.4 11.35.1 2.7 14.35.4 2.9 18.1
Langmuir experimental
Ce qe Ce/qe Ce13.8 2.2 6.3 13.833.9 3.8 8.9 33.966.7 6.8 9.8 66.7
117.4 11.1 10.6 117.4157.1 14.4 10.9 157.1221.7 18.3 12.1 221.7
Langmuir teóricoCe Ce/qe qe
13.8 7.7 1.833.9 8.2 4.166.7 9.0 7.4
117.4 10.1 11.6157.1 11.0 14.2221.7 12.5 17.7
pH=2.0 Norit%R Ce qe
47.6 5.814 10.654.4 10.242 24.444.0 22.332 35.145.9 33.19 56.349.5 41.35 81.147.9 50.382 92.6
0 10 20 30 40 50 600.0
10.020.030.040.050.060.070.080.090.0
100.0
Ce(mg.dm-3)
qe(m
g.g-
1)
1.5 2 2.5 3 3.5 4 4.5 50.5
1.0
1.5
2.0
2.5
3.0
3.5
Freundlich
Exp. pH=2,0
LnCe
Lnqe
1.5 2 2.5 3 3.5 4 4.5 50.5
1.0
1.5
2.0
2.5
3.0
3.5
1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.00.5
1.0
1.5
2.0
2.5
3.0
3.5
Ce/qe2.12.22.6
33.2
4
1.5 2 2.5 3 3.5 4 4.5 50.5
1.0
1.5
2.0
2.5
3.0
3.5
0 10 20 30 40 50 60 70 80 90 1002
2.5
3
3.5
4
4.5
Cemg.dm-3
qem
g.g-
1
0 20 40 60 80 100 1202.0
2.5
3.0
3.5
4.0
4.5
pH=2.0 Merck%R Ce qe
80.8 19.4 282.8 33 479.4 79.2 7.682.2 103.3 11.975.1 187.3 14.175.0 266.7 20
0 50 100 150 200 250 3000
5
10
15
20
25
Cemg.dm-3
qem
g.g-
1
2.5 3.0 3.5 4.0 4.5 5.0 5.5 6.00.5
1.0
1.5
2.0
2.5
3.0
3.5
2.5 3 3.5 4 4.5 5 5.5 60.5
1.0
1.5
2.0
2.5
3.0
3.5
2.5 3 3.5 4 4.5 5 5.5 60.5
1.0
1.5
2.0
2.5
3.0
3.5
Freundlich
Exp. pH=2,0
LnCeLn
qe
Ce/qe9.78.3
10.48.7
13.313.3
2.5 3 3.5 4 4.5 5 5.5 60.5
1.0
1.5
2.0
2.5
3.0
3.5
0 50 100 150 200 250 3008
9
10
11
12
13
14
0 50 100 150 200 250 3008.0
9.0
10.0
11.0
12.0
13.0
14.0
pH=4.0 Norit%R Ce qe
96.8 3.2 2.496.7 6.1 4.597.3 9.3 8.396.7 18.5 13.694.3 41.8 17.391.3 83.1 21.8
0 10 20 30 40 50 60 70 80 900
5
10
15
20
25
Ce(mg.dm-3)
qe(m
g.g-
1)
0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.00.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
1 1.5 2 2.5 3 3.5 4 4.5 50.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
0 0.5 1 1.5 2 2.5 3 3.5 4 4.5 50.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
Freundlich
Exp. pH=4,0
LnCe
Lnqe
Ce/qe1.31.41.11.42.43.8
1 1.5 2 2.5 3 3.5 4 4.5 50.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
0 10 20 30 40 50 60 70 80 900
0.5
1
1.5
2
2.5
3
3.5
4
0 10 20 30 40 50 60 70 80 900.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
pH=4.0 Merck%R Ce qe
86.2 13.8 2.281.6 33.9 3.880.4 66.7 6.879.1 117.4 11.178.6 157.1 14.476.8 221.7 18.3
0 50 100 150 200 2500.0
2.0
4.0
6.0
8.0
10.0
12.0
14.0
16.0
18.0
20.0
Ce(mg.dm-3)
qe(m
g.g-
1)
2.0 2.5 3.0 3.5 4.0 4.5 5.0 5.5 6.00.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
2 2.5 3 3.5 4 4.5 5 5.5 60.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
0 10 20 30 40 50 60 70 80 900.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Ce/qe6.38.99.8
10.610.912.1
2 2.5 3 3.5 4 4.5 5 5.5 60.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
0 50 100 150 200 2505
6
7
8
9
10
11
12
13
0 50 100 150 200 2505.0
6.0
7.0
8.0
9.0
10.0
11.0
12.0
13.0
0 50 100 150 200 2505.0
6.0
7.0
8.0
9.0
10.0
11.0
12.0
13.0
Co qe11.1 10.6
22.45 24.439.9 35.1
61.34 56.381.9 81.196.7 92.6
Ce5
1023.341.156.497.1
0 10 20 30 40 50 600.0
10.020.030.040.050.060.070.080.090.0
100.0
Ce(mg.dm-3)
qe(m
g.g-
1)
0 20 40 60 80 100 1200.0
10.0
20.0
30.0
40.0
50.0
60.0
70.0
80.0
90.0
100.0
f(x) = 0.959720052092039 x − 0.101111187520658R² = 0.994096141684796
Co (mg.dm-3)
qe(m
g.g-
1)
1.5 2 2.5 3 3.5 4 4.5 50.5
1.0
1.5
2.0
2.5
3.0
3.5
Freundlich
Exp. pH=2,0
LnCe
Lnqe
0 20 40 60 80 100 1202.0
2.5
3.0
3.5
4.0
4.5
0 10 20 30 40 50 60 70 80 90 1002.0
2.5
3.0
3.5
4.0
4.5
Langmuir
Exp. pH=2,0
Cemg.dm-3
qem
g.g-
1
Co qe100.8 2191.4 4384.9 7.6579.3 11.9751.1 14.1
1064.9 20
Ce19.4
3379.2
103.3187.3266.7
0 50 100 150 200 250 3000
5
10
15
20
25
Cemg.dm-3
qem
g.g-
1
2.5 3 3.5 4 4.5 5 5.5 60.5
1.0
1.5
2.0
2.5
3.0
3.5
Freundlich
Exp. pH=2,0
LnCe
Lnqe
0 50 100 150 200 250 3008.0
9.0
10.0
11.0
12.0
13.0
14.0
Langmuir
Exp. pH=2,0
Ce(mg.dm-3)
qe(m
g.g-
1)
Co qe99.9 2.4
184.2 4.5340.1 8.3561.7 13.6734.3 17.3955.5 21.8
0 10 20 30 40 50 60 70 80 900
5
10
15
20
25
Ce(mg.dm-3)
qe(m
g.g-
1)
0 0.5 1 1.5 2 2.5 3 3.5 4 4.5 50.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
Freundlich
Exp. pH=4,0
LnCe
Lnqe
0 10 20 30 40 50 60 70 80 900.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Langmuir
Exp. pH=4,0
Ce(mg.dm-3)
qe(m
g.g-
1)
Co qe99.9 2.2
184.2 3.8340.1 6.8561.7 11.1734.3 14.4955.5 18.3
0 50 100 150 200 2500.0
2.0
4.0
6.0
8.0
10.0
12.0
14.0
16.0
18.0
20.0
Ce(mg.dm-3)
qe(m
g.g-
1)
2 2.5 3 3.5 4 4.5 5 5.5 60.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
Freundlich
Exp. pH=4,0
LnCe
Lnqe
0 50 100 150 200 2505.0
6.0
7.0
8.0
9.0
10.0
11.0
12.0
13.0
Langmuir
Exp. pH=4,0
Ce(mg.dm-3)
qe(m
g.g-
1)
Co %R11.1 47.6
22.45 54.439.9 44.0
61.34 45.981.9 49.596.7 47.9
qe2.54.48.2
13.116.626.5
0 20 40 60 80 100 1200.0
10.0
20.0
30.0
40.0
50.0
60.0
70.0
80.0
90.0
100.0
f(x) = 0.959720052092039 x − 0.101111187520658R² = 0.994096141684796
Co (mg.dm-3)
qe(m
g.g-
1)
0 20 40 60 80 100 1200
102030405060708090
100
Modelo de Freundlich
Experimental
Ce(mg.dm-3)
qe(m
g.g-
1)
Ce qe5 2.3
10 4.423.3 9.241.1 14.356.4 17.797.1 24.3
0 20 40 60 80 100 1200
10
20
30
40
50
60
70
80
90
100
Modelo de Langmuir
Experimental
Ce(mg.dm-3)
qe(m
g.g-
1)
Co %R100.8 80.8191.4 82.8384.9 79.4579.3 82.2751.1 75.1
1064.9 75
qe2.54.48.2
13.116.526.5
0 200 400 600 800 1000 12000
5
10
15
20
25
Comg.dm-3
qem
g.g-
1
0 50 100 150 200 250 3000
5
10
15
20
25
30
Modelo de Freundlich
Experimental
Cemg.dm-3
qem
g.g-
1
Ce qe5 2.3
10 4.423.3 9.241.1 14.356.4 17.797.1 24.3
0 20 40 60 80 100 1200
10
20
30
40
50
60
70
80
90
100
Modelo de Langmuir
Experimental
Ce(mg.dm-3)
qe(m
g.g-
1)
Co99.9
184.2340.1561.7734.3955.5
Ce qe3.2 36.1 4.69.3 6.1
18.5 9.841.8 1783.1 27
0 200 400 600 800 1000 12000
5
10
15
20
25
Co(mg.dm-3)
qe(m
g.g-
1)
0 10 20 30 40 50 60 70 80 900
5
10
15
20
25
30
Ce(mg.dm-3)
qe(m
g.g-
1)
Ce qe3.2 2.96.1 5.19.3 7.1
18.5 11.441.8 17.583.1 22.2
0 10 20 30 40 50 60 70 80 900
5
10
15
20
25
Ce(mg.dm-3)
qe(m
g.g-
1)
Co99.9
184.2340.1561.7734.3955.5
Ce qe13.8 233.9 4.166.7 7.1
117.4 11.3157.1 14.3221.7 18.1
0 100 200 300 400 500 600 700 800 900 10000.0
2.0
4.0
6.0
8.0
10.0
12.0
14.0
16.0
18.0
20.0
Co(mg.dm-3)
qe(m
g.g-
1)
0 50 100 150 200 2500
2
4
6
8
10
12
14
16
18
20
Ce(mg.dm-3)
qe(m
g.g-
1)
Ce qe13.8 1.833.9 4.166.7 7.4
117.4 11.6157.1 14.2221.7 17.7
0 50 100 150 200 2500
2
4
6
8
10
12
14
16
18
20
Ce(mg.dm-3)
qe(m
g.g-
1)
0 20 40 60 80 100 1200.0
10.0
20.0
30.0
40.0
50.0
60.0
Co(mg.dm-3)
% d
e re
moc
ión
de P
b2+
0 20 40 60 80 100 1200
10
20
30
40
50
60
70
80
90
100
Modelo de Langmuir
Experimental
Ce(mg.dm-3)
qe(m
g.g-
1)
0 50 100 150 200 250 3000
5
10
15
20
25
30
Modelo de Freundlich
Experimental
Cemg.dm-3
qem
g.g-
1
0 200 400 600 800 100069
72
75
78
81
84
Co(mg.dm-3)
% d
e re
moc
ión
de P
b2+
0 20 40 60 80 100 1200
10
20
30
40
50
60
70
80
90
100
Modelo de Langmuir
Experimental
Ce(mg.dm-3)
qe(m
g.g-
1)
%R97.896.796.796.394.391.3
0 10 20 30 40 50 60 70 80 900
5
10
15
20
25
30
Ce(mg.dm-3)
qe(m
g.g-
1)
0 200 400 600 800 1000 120088
90
92
94
96
98
100
Co(mg.dm-3)
% d
e re
moc
ión
de P
b2+
0 10 20 30 40 50 60 70 80 900
5
10
15
20
25
Ce(mg.dm-3)
qe(m
g.g-
1)
%R86.281.680.479.178.676.8
0 100 200 300 400 500 600 700 800 900 100070
72
74
76
78
80
82
84
86
88
Co(mg.dm-3)
% d
e re
moc
ión
de P
b2+
0 50 100 150 200 2500
2
4
6
8
10
12
14
16
18
20
Ce(mg.dm-3)
qe(m
g.g-
1)
0 50 100 150 200 2500
2
4
6
8
10
12
14
16
18
20
Ce(mg.dm-3)
qe(m
g.g-
1)
qe(exp) qe(teo) Freundlich2.4 2.5 -5.3 5.34.5 4.4 2.9 2.9
9 8.2 9.1 9.113.5 13.1 3.1 3.117.4 16.5 4.9 4.924.2 26.5 -9.4 9.4
5.8
qe(exp) qe(teo) Langmuir2.4 2.3 4.2 4.24.5 4.4 2.2 2.2
9 9.3 -3.3 3.313.5 14.3 -5.9 5.917.4 17.7 -1.7 1.724.2 24.3 -0.4 0.4
2.9
qe(exp) qe(teo)2.0 2.4 -17.9 17.94.0 3.7 6.6 6.67.6 7.8 -2.1 2.1
11.9 9.2 22.7 22.714.1 15.3 -8.5 8.520.0 21.5 -7.7 7.7
10.9
qe(exp) qe(teo)2 2.2 -10.0 104 3.7 7.5 7.5
7.6 8 -5.3 5.311.9 9.9 16.8 16.814.1 15.5 -9.9 9.9
20 19.5 2.5 2.58.7
qe(exp) qe(teo) Freundlich2.4 3.2 -33.3 33.34.5 4.8 -6.7 6.78.3 6.2 25.3 25.3
13.6 10 26.5 26.517.3 17 1.7 1.721.8 27.1 -24.3 24.3
19.6
qe(exp) qe(teo) Langmuir2.4 2.9 -20.8 20.84.5 5.1 -13.3 13.38.3 7.1 14.5 14.5
13.6 11.4 16.2 16.217.3 17.5 -1.2 1.221.8 22.2 -1.8 1.8
11.3
qe(exp) qe(teo)2.2 2 9.1 9.13.8 4.1 -7.9 7.96.8 7.1 -4.4 4.4
11.1 11.3 -1.8 1.814.4 14.3 0.7 0.718.3 18.1 1.1 1.1
4.2
qe(exp) qe(teo)2.2 1.8 18.2 18.23.8 4.1 -7.9 7.96.8 7.4 -8.8 8.8
11.1 11.6 -4.5 4.514.4 14.2 1.4 1.418.3 17.7 3.3 3.3
7.4
NORIT pH=2,0/4,0Co qe Co qe
100.8 2.4 99.9 2.4191.4 4.5 184.2 4.5384.9 9 340.1 8.3579.3 13.5 561.7 13.6751.1 17.4 734.3 17.3
1064.9 24.2 955.5 21.8
NORIT pH=2,0/4,0Co %R Co %R
100.8 95 99.9 96.8191.4 94.8 184.2 96.7384.9 93.9 340.1 97.3579.3 92.9 561.7 96.7751.1 92.5 734.3 94.3
1064.9 90.9 955.5 91.3
Capacidad de remoción con respecto a Co
Porcentaje de remoción con respecto a Co
0 200 400 600 800 1000 12000
5
10
15
20
25
0 200 400 600 800 1000 12000
5
10
15
20
25
0 200 400 600 800 1000 12000
5
10
15
20
25
30
Norit pH=2,0
Norit pH=4,0
(b) Co(mg.dm-3)
qe(m
g.g-
1)
0 200 400 600 800 1000 120086
88
90
92
94
96
98
Norit pH=2,0
Norit pH=4,0
(a) Co(mg.dm-3)
% d
e re
moc
ión
de P
b2+
NORIT pH=2,0/4,0Ce qe Ce qe
5 2.4 3.2 2.410 4.5 6.1 4.5
23.3 9 9.3 8.341.1 13.5 18.5 13.656.4 17.4 41.8 17.397.1 24.2 83.1 21.8
Capacidad de remoción con respecto a Ce
0 10 20 30 40 50 60 70 80 90 1000
5
10
15
20
25
30
Norit pH=2.0
0 10 20 30 40 50 60 70 80 90 1000.0
5.0
10.0
15.0
20.0
25.0
30.0
Norit pH=2.0
Norit pH=4.0
Ce(mg.dm-3)
qe(m
g.g-
1)
0 10 20 30 40 50 60 70 80 900
5
10
15
20
25
30
Norit pH=4.0
0 200 400 600 800 1000 120087
88
89
90
91
92
93
94
95
96
97
98
0 200 400 600 800 1000 120088
89
90
91
92
93
94
95
96
97
98
0 200 400 600 800 1000 120086
88
90
92
94
96
98
Norit pH=2,0
Norit pH=4,0
(a) Co(mg.dm-3)
% d
e re
moc
ión
de P
b2+
0 10 20 30 40 50 60 70 80 90 1000
5
10
15
20
25
30
Norit pH=2.0
0 10 20 30 40 50 60 70 80 900
5
10
15
20
25
30
Norit pH=4.0
MERCK pH=2,0/4,0Co qe
100.8 2191.4 4384.9 7.6579.3 11.9751.1 14.1
1064.9 20
MERCK pH=2,0/4,0Co %R
100.8 80.8191.4 82.8384.9 79.4579.3 82.2751.1 75.1
1064.9 75
Capacidad de remoción con respecto a Co
Porcentaje de remoción con respecto a Co
0 200 400 600 800 1000 12000
5
10
15
20
25
0 200 400 600 800 1000 12000
5
10
15
20
25
30
Norit pH=2,0
Norit pH=4,0
(b) Co(mg.dm-3)
qe(m
g.g-
1)
0 200 400 600 800 1000 120086
88
90
92
94
96
98
Norit pH=2,0
Norit pH=4,0
(a) Co(mg.dm-3)
% d
e re
moc
ión
de P
b2+
0 200 400 600 800 1000 12000
5
10
15
20
25
MERCK pH=2,0/4,0Ce qe
19.4 233 4
79.2 7.6103.3 11.9187.3 14.1266.7 20
Capacidad de remoción con respecto a Ce
0 10 20 30 40 50 60 70 80 90 1000.0
5.0
10.0
15.0
20.0
25.0
30.0
Norit pH=2.0
Norit pH=4.0
Ce(mg.dm-3)
qe(m
g.g-
1)
0 10 20 30 40 50 60 70 80 900
5
10
15
20
25
30
Norit pH=4.0
0 50 100 150 200 250 3000
5
10
15
20
25
Merck pH=2,0
0 200 400 600 800 1000 120088
89
90
91
92
93
94
95
96
97
98
0 200 400 600 800 1000 120086
88
90
92
94
96
98
Norit pH=2,0
Norit pH=4,0
(a) Co(mg.dm-3)
% d
e re
moc
ión
de P
b2+
0 200 400 600 800 1000 120068
70
72
74
76
78
80
82
84
86
88
0 10 20 30 40 50 60 70 80 900
5
10
15
20
25
30
Norit pH=4.0
0 50 100 150 200 250 3000
5
10
15
20
25
Merck pH=2,0
MERCK pH=2,0/4,0Co qe
99.9 2.2184.2 3.8340.1 6.8561.7 11.1734.3 14.4955.5 18.3
MERCK pH=2,0/4,0Co %R
99.9 86.2184.2 81.6340.1 80.4561.7 79.1734.3 78.6955.5 76.8
Capacidad de remoción con respecto a Co
Porcentaje de remoción con respecto a Co
0 200 400 600 800 1000 12000
5
10
15
20
25
0 200 400 600 800 1000 12000
5
10
15
20
25
0 200 400 600 800 1000 12000
5
10
15
20
25
Merck pH=2,0
Merck pH=4,0
(b) Co(mg.dm-3)
qe(m
g.g-
1)
0 200 400 600 800 1000 120074
76
78
80
82
84
86
88Merck pH=2,0
Merck pH=4,0
(a) Co(mg.dm-3)
% d
e re
moc
ión
de P
b2+
MERCK pH=2,0/4,0Ce qe
13.8 2.233.9 3.866.7 6.8
117.7 11.1157.1 14.4221.7 18.3
Capacidad de remoción con respecto a Ce
0 50 100 150 200 250 3000
5
10
15
20
25
Merck pH=2,0
Merck pH=4,0
Ce(mg.dm-3)
qe(m
g.g-
1)
0 50 100 150 200 250 3000
5
10
15
20
25
Merck pH=2,0
0 50 100 150 200 250 3000
5
10
15
20
25
Merck pH=4,0
0 200 400 600 800 1000 120068
70
72
74
76
78
80
82
84
86
88
0 200 400 600 800 1000 120074
76
78
80
82
84
86
88
0 200 400 600 800 1000 120074
76
78
80
82
84
86
88Merck pH=2,0
Merck pH=4,0
(a) Co(mg.dm-3)
% d
e re
moc
ión
de P
b2+
0 50 100 150 200 250 3000
5
10
15
20
25
Merck pH=2,0
0 50 100 150 200 250 3000
5
10
15
20
25
Merck pH=4,0
0 200 400 600 800 1000 12000
5
10
15
20
25
0 200 400 600 800 1000 12000
5
10
15
20
25
Merck pH=2,0
Merck pH=4,0
(b) Co(mg.dm-3)
qe(m
g.g-
1)
0 200 400 600 800 1000 120074
76
78
80
82
84
86
88Merck pH=2,0
Merck pH=4,0
(a) Co(mg.dm-3)
% d
e re
moc
ión
de P
b2+
0 50 100 150 200 250 3000
5
10
15
20
25
Merck pH=2,0
Merck pH=4,0
Ce(mg.dm-3)
qe(m
g.g-
1)
0 50 100 150 200 250 3000
5
10
15
20
25
Merck pH=4,0
0 200 400 600 800 1000 120074
76
78
80
82
84
86
88
0 200 400 600 800 1000 120074
76
78
80
82
84
86
88Merck pH=2,0
Merck pH=4,0
(a) Co(mg.dm-3)
% d
e re
moc
ión
de P
b2+
0 50 100 150 200 250 3000
5
10
15
20
25
Merck pH=4,0
NORIT pH=2,0 NORIT pH= 4,0Co Ce Co-Ce qe %R Co Ce
100.8 5 95.8 2.4 95 99.9 3.2191.4 10 181.4 4.5 94.8 184.2 6.1384.9 23.3 361.6 9 93.9 340.1 9.3579.3 41.1 538.2 13.5 92.9 561.7 18.5751.1 56.4 694.7 17.4 92.5 734.3 41.8
1064.9 97.1 967.8 24.2 90.9 955.5 83.1
FREUNDLICH EXP. FREUNDLICH TEO. FREUNDLICH EXP.LnCe Lnqe LnCe Lnqe LnCe Lnqe
1.6 0.9 1.6 0.9 1.2 0.92.3 1.5 2.3 1.5 1.8 1.53.1 2.2 3.1 2.1 2.2 2.13.7 2.6 3.7 2.6 2.9 2.6
4 2.9 4 2.8 3.7 2.94.6 3.2 4.6 3.3 4.4 3.1
LANGMUIR EXP. LANGMUIR TEO. LANGMUIR EXP.Ce Ce/qe Ce Ce/qe Ce Ce/qe
5 2.1 5 2.2 3.2 1.310 2.2 10 2.3 6.1 1.4
23.3 2.6 23.3 2.5 9.3 1.141.1 3 41.1 2.9 18.5 1.456.4 3.2 56.4 3.2 41.8 2.497.1 4 97.1 4 83.1 3.8
Co %R100.8 95191.4 94.8384.9 93.9579.3 92.9751.1 92.5
1064.9 90.9
0 200 400 600 800 1000 120088
89
90
91
92
93
94
95
96
Co qe100.8 2.4191.4 4.5384.9 9579.3 13.5751.1 17.4
1064.9 24.2
Ce qe5 2.4
10 4.523.3 941.1 13.556.4 17.497.1 24.2
0 200 400 600 800 1000 120088
89
90
91
92
93
94
95
96
0 200 400 600 800 1000 12000
5
10
15
20
25
30
0 20 40 60 80 100 1200
5
10
15
20
25
30
NORIT pH= 4,0 MERCK pH=2,0Co-Ce qe %R Co Ce Co-Ce qe
96.7 2.4 96.8 100.8 19.4 81.4 2178.1 4.5 96.7 191.4 33 158.4 4330.8 8.3 97.3 384.9 79.2 305.7 7.6543.2 13.6 96.7 579.3 103.3 476 11.9692.5 17.3 94.3 751.1 187.3 563.8 14.1872.4 21.8 91.3 1064.9 266.7 798.2 20
FREUNDLICH TEO. FREUNDLICH EXP. FREUNDLICH TEO.LnCe Lnqe LnCe Lnqe LnCe
1.2 1.2 3 0.7 1.21.8 1.6 3.5 1.4 1.82.2 1.8 4.4 2 2.22.9 2.3 4.6 2.5 2.93.7 2.8 5.2 2.6 3.74.4 3.3 5.6 3 4.4
LANGMUIR TEO. LANGMUIR EXP. LANGMUIR TEO.Ce Ce/qe Ce Ce/qe Ce
3.2 1.1 19.4 9.7 19.46.1 1.2 33 8.3 339.3 1.3 79.2 10.4 79.2
18.5 1.6 103.3 8.7 103.341.8 2.4 187.3 13.3 187.383.1 3.7 266.7 13.3 266.7
Co %R100.8 80.8191.4 82.8384.9 79.4579.3 82.2751.1 75.1
1064.9 75
0 200 400 600 800 1000 120088
89
90
91
92
93
94
95
96
0 200 400 600 800 1000 120070
72
74
76
78
80
82
84
Co qe100.8 2191.4 4384.9 7.6579.3 11.9751.1 14.1
1064.9 20
Ce qe19.4 2
33 479.2 7.6
103.3 11.9187.3 14.1266.7 20
0 200 400 600 800 1000 120088
89
90
91
92
93
94
95
96
0 200 400 600 800 1000 12000
5
10
15
20
25
30
0 200 400 600 800 1000 120070
72
74
76
78
80
82
84
0 20 40 60 80 100 1200
5
10
15
20
25
30
0 200 400 600 800 1000 12000
5
10
15
20
25
0 50 100 150 200 250 3000
5
10
15
20
25
MERCK pH=2,0 MERCK pH=4,0%R Co Ce Co-Ce qe %R
80.8 99.9 13.8 86.1 2.2 86.282.8 184.2 33.9 150.3 3.8 81.679.4 340.1 66.7 273.4 6.8 80.482.2 561.7 117.7 444.3 11.1 79.175.1 734.3 157.1 577.2 14.4 78.6
75 955.5 221.7 733.8 18.3 76.8
FREUNDLICH TEO. FREUNDLICH EXP. FREUNDLICH TEO.Lnqe LnCe Lnqe LnCe Lnqe
0.9 2.6 0.8 2.6 0.71.3 3.5 1.3 3.5 1.42.1 4.2 1.9 4.2 22.2 4.8 2.4 4.8 2.42.7 5.1 2.7 5.1 2.73.1 5.4 2.9 5.4 2.9
LANGMUIR TEO. LANGMUIR EXP. LANGMUIR TEO.Ce/qe Ce Ce/qe Ce Ce/qe
8.7 13.8 6.3 13.8 7.79 33.9 8.9 33.9 8.2
9.9 66.7 9.8 66.7 910.4 117.7 10.6 117.7 10.112.1 157.1 10.9 157.1 1113.7 221.7 12.1 221.7 12.5
0 200 400 600 800 1000 120070
72
74
76
78
80
82
84
0 200 400 600 800 1000 120070
72
74
76
78
80
82
84
0 200 400 600 800 1000 12000
5
10
15
20
25
0 50 100 150 200 250 3000
5
10
15
20
25